Pincer versus pseudopincer: isomerism in palladium(II) complexes bearing κ(3)C,S,C ligands.

نویسندگان

  • Jan Christopher Bernhammer
  • Gilles Frison
  • Han Vinh Huynh
چکیده

In NHC pincer complexes incorporating a hemilabile donor site, there exists an equilibrium between the true pincer form and a pseudopincer coordination isomer. The influence of the NHC moieties on this isomerism has been studied by DFT calculations.

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عنوان ژورنال:
  • Dalton transactions

دوره 43 23  شماره 

صفحات  -

تاریخ انتشار 2014